Dynamic structure elucidation of chemical reactivity by laser pulses and X-ray probes.

نویسندگان

  • Stuart A Bartlett
  • Michelle L Hamilton
  • John Evans
چکیده

Visualising chemical reactions by X-ray methods is a tantalising prospect. New light sources provide the prospect for studying atomic, electronic and energy transfers accompanying chemical change by X-ray spectroscopy and inelastic scattering. Here we assess how this adventure can illuminate inorganic and catalytic chemistry. In particular X-ray inelastic scattering provides a means of exploiting X-ray free electron lasers, as a parallel to laser Raman spectroscopy.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Growth, Characterization of Cu Nanoparticles Thin Film by Nd: YAG Laser Pulses Deposition

We report the growth and characterization of Cu nanoparticles thin film of on glass substrate by pulse laser deposition method. The Cu thin film prepared with different energy 50, 60, 70, and 80 mJ. The energy effect on the morphological, structural and optical properties were studied by AFM, XRD and UV-Visible spectrophotometer. Surface topography studied by atomic force microscopy revealed na...

متن کامل

بررسی نرخ رشد یک لیزر الکترون آزاد با نوسان‌ساز لیزری و پس زمینه پلاسما

In this paper, a free-electron laser (FEL) growth rate with a laser wiggler in which plasma background is used to generate short wavelengths in x-ray regimes, has been investigated theoretically. A linearly polarized laser pulse, due to having short wiggler periods (inrange) is able to produce coherent radiations in x-ray regions and can be applied as a planar wiggler in a FEL. Phase velocity o...

متن کامل

One-pot synthesis of Ag/Fe3O4 nanocomposite: Preparation, characterization and efficient catalyst

In this study, nanometer sized of Ag/Fe3O4 nanocomposite (AFN) have been synthesized by using a simple and based on chemical reduction method. The size and shape of (AFN) controlled by using of condensation (Fe2O3 (2.975 mmol), NaBH4 (21.25 mmol), AgNO3 (2.532 mmol) and polyvinylpyrrolidone (PVP) (8.925 mmol K30 Mr=10.000) in 40 ºC. The synthesized AFN was characterized by XRD, scanning electro...

متن کامل

تاثیر استفاده از پیش پالس و هدف نانوساختار بر میزان گسیل پرتو ایکس از پلاسمای تولید شده به وسیله لیزرهای پرتوان

In this paper, the enhanced continuum x-ray emission from nano-targets irradiated by long laser pulses is investigated numerically. The calculations are performed under different prepulse conditions, and the x-ray emissions from solid and nano-structured target are compared. The results show that x-ray yield can be enhanced significantly using a nano-layer with appropriate density. In addition,...

متن کامل

Energy-dispersive X-ray emission spectroscopy using an X-ray free-electron laser in a shot-by-shot mode.

The ultrabright femtosecond X-ray pulses provided by X-ray free-electron lasers open capabilities for studying the structure and dynamics of a wide variety of systems beyond what is possible with synchrotron sources. Recently, this "probe-before-destroy" approach has been demonstrated for atomic structure determination by serial X-ray diffraction of microcrystals. There has been the question wh...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Dalton transactions

دوره 44 14  شماره 

صفحات  -

تاریخ انتشار 2015